Pulsed laser deposition of ZnO nanocluster films by Cu-vapor laser

被引：30

作者：

Dinh, LN ^{[1
]}

Schildbach, MA ^{[1
]}

Balooch, M ^{[1
]}

McLean, W ^{[1
]}

机构：

[1] Lawrence Livermore Natl Lab, Livermore, CA 94551 USA

来源：

JOURNAL OF APPLIED PHYSICS | 1999年 / 86卷 / 02期

关键词：

D O I：

10.1063/1.370857

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

The dependence of stoichiometry, grain size, cathodoluminescence colors, adhesion, and surface morphology of zinc oxide films, deposited by a Cu-vapor laser at room temperature, as a function of oxygen ambient pressure during synthesis were investigated. Auger electron spectroscopy showed that ZnO films with a Zn/O ratio close to 1 were obtained at oxygen pressures > 10(-1) Torr. X-ray diffraction revealed that pulsed laser deposited zinc oxide films were composed mainly of nanocrystals, the average grain size of which grew from 5 to 17.5 nm as the oxygen pressure was increased from 10(-5) to 1 Torr. The surface morphology of the films, as determined by secondary electron microscopy, also exhibited increasing roughness as the grain size increased. Films grown in an oxygen pressure > 1.5x10(-1) Torr glowed blue under electron bombardment, while slightly substoichiometric films glowed white under similar excitation. Films deposited in an oxygen background pressure up to 1.5x10(-1) Torr exhibited good adhesion to substrates. Deposition rate on the order of 4.6 nm/s was obtained. (C) 1999 American Institute of Physics. [S0021-8979(99)06314-8].

引用

页码：1149 / 1152

页数：4

共 16 条

[1] Reactions of laser-ablated Zn and Cd atoms with O-2: Infrared spectra of ZnO, OZnO, CdO, and OCdO in solid argon [J].