Controlling the formation of 1 out of 64 stereoisomers using organocatalysis

被引：42

作者：

Bertelsen, Soren ^{[1
]}

Johansen, Rasmus L. ^{[1
]}

Jorgensen, Karl Anker ^{[1
]}

机构：

[1] Aarhus Univ, Danish Natl Res Fdn, Ctr Catalysis, Dept Chem, DK-8000 Aarhus, Denmark

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 26期

关键词：

D O I：

10.1039/b806418k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The formation of 1 out of 64 stereoisomers, i.e. controlling the creation of 6 stereocenters, of important optically active bicyclo[ 3.3.1] non-2-ene compounds, has been achieved using organocatalysis; the reaction proceeds with excellent stereocontrol and can be carried out with the generation of enantiopure products using chromatography-free procedures.

引用

页码：3016 / 3018

页数：3

共 31 条

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