Molten state and solvent-free systems studied by NMR spectroscopy: addition reactions catalyzed by transition metal complexes

被引：6

作者：

Ananikov, V. P. ^{[1
]}

Beletskaya, I. P. ^{[2
]}

机构：

[1] Russian Acad Sci, ND Zelinsky Inst Organ Chem, Moscow 119991, Russia

[2] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2008年 / 57卷 / 04期

基金：

俄罗斯基础研究基金会;

关键词：

NMR spectroscopy; solvent-free reactions; molten state reactions; transition metal catalysis; alkynes;

D O I：

10.1007/s11172-008-0114-8

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the present review we address scarcely studied application area of NMR spectroscopy investigation of molten state and solvent-free systems. In such a case NMR spectra are recorded without a solvent and without magnetic field stabilization on any nucleus. Taking Our recent studies of catalytic addition of sulfur- and selenium-containing compounds to alkynes as examples, we describe most important practical aspects of NMR studies and their application for solving important chemical problems.

引用

页码：754 / 760

页数：7

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