Catalysis in capillaries by Pd thin films using microwave-assisted continuous-flow organic synthesis (MACOS)

被引：148

作者：

Shore, G ^{[1
]}

Morin, S ^{[1
]}

Organ, MG ^{[1
]}

机构：

[1] York Univ, Dept Chem, N York, ON M3J 1P3, Canada

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 17期

关键词：

cross-coupling; microwaves; palladium; synthetic methods; thin films;

D O I：

10.1002/anie.200503600

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Finally ... metal in a microwave! Thin films of Pd black deposited onto the inner surface of microcapillaries are efficient for metal-catalyzed transformations under flow conditions including the Suzuki-Miyama and Heck couplings. The reaction mixture is flowed through these miniature capillaries while being microwaved, and conversion times are on the order of seconds. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2761 / 2766

页数：6

共 36 条

[1] Practical use of continuous processing in developing and scaling up laboratory processes
Anderson, NG
[J]. ORGANIC PROCESS RESEARCH & DEVELOPMENT, 2001, 5 (06) : 613 - 621
[2] A simple continuous flow microwave reactor
Bagley, MC
Jenkins, RL
Lubinu, MC
Mason, C
Wood, R
[J]. JOURNAL OF ORGANIC CHEMISTRY, 2005, 70 (17) : 7003 - 7006
[3] A microcapillary system for simultaneous, parallel microwave-assisted synthesis
Comer, E
Organ, MG
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2005, 11 (24) : 7223 - 7227
[4] A microreactor for microwave-assisted capillary (continuous flow) organic synthesis
Comer, E
Organ, MG
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (22) : 8160 - 8167
[5] On-microchip multiphase chemistry - a review of microreactor design principles and reagent contacting modes
Doku, GN
Verboom, W
Reinhoudt, DN
van den Berg, A
[J]. TETRAHEDRON, 2005, 61 (11) : 2733 - 2742
[6] Ehrfeld W., 2000, Microreactors: new technology for modern chemistry, DOI DOI 10.1002/3527601953
[7] PREPARATION AND CHARACTERIZATION OF BIMETALLIC PD-CU COLLOIDS BY THERMAL-DECOMPOSITION OF THEIR ACETATE COMPOUNDS IN ORGANIC-SOLVENTS
ESUMI, K
TANO, T
TORIGOE, K
MEGURO, K
[J]. CHEMISTRY OF MATERIALS, 1990, 2 (05) : 564 - 567
[8] PREPARATION OF ORGANOPALLADIUM PARTICLES FROM THERMAL-DECOMPOSITION OF ITS ORGANIC-COMPLEX IN ORGANIC-SOLVENTS
ESUMI, K
TANO, T
MEGURO, K
[J]. LANGMUIR, 1989, 5 (01) : 268 - 270
[9] DISPERSION OF UNIFORMLY SIZED PALLADIUM PARTICLES IN ORGANIC-SOLVENTS
ESUMI, K
SUZUKI, M
TANO, T
TORIGOE, K
MEGURO, K
[J]. COLLOIDS AND SURFACES, 1991, 55 : 9 - 14
[10] PREPARATION OF PLATINUM PARTICLES BY THERMAL-DECOMPOSITION OF PLATINUM COMPLEX IN ORGANIC-SOLVENT
ESUMI, K
SADAKANE, O
TORIGOE, K
MEGURO, K
[J]. COLLOIDS AND SURFACES, 1992, 62 (03): : 255 - 257

← 1 2 3 4 →