An unsymmetrical pentacene derivative with ambipolar behavior in organic thin-film transistors

被引：25

作者：

Etschel, Sebastian H. ^{[1
,2
,3
]}

Waterloo, Andreas R. ^{[1
,2
]}

Margraf, Johannes T. ^{[4
]}

Amin, Atefeh Y. ^{[3
]}

Hampel, Frank ^{[1
,2
]}

Jaeger, Christof M. ^{[4
]}

Clark, Timothy ^{[4
]}

Halik, Marcus ^{[3
]}

Tykwinski, Rik R. ^{[1
,2
]}

机构：

[1] Univ Erlangen Nurnberg, Dept Chem & Pharm, D-91054 Erlangen, Germany

[2] Univ Erlangen Nurnberg, Interdisciplinary Ctr Mol Mat, D-91054 Erlangen, Germany

[3] Univ Erlangen Nurnberg, Inst Polymer Mat Organ Mat & Devices, D-91058 Erlangen, Germany

[4] Univ Erlangen Nurnberg, Comp Chem Ctr, D-91052 Erlangen, Germany

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 60期

关键词：

ELECTRONIC-PROPERTIES; ACENES;

D O I：

10.1039/c3cc43270j

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

Three new unsymmetrical anthracenyl-pentacene derivatives have been synthesized, characterized using X-ray crystallography, and used as semiconductors in OTFTs. For one derivative, ambipolar charge carrier transport was observed with a hole mobility of 0.2 cm(2) V-1 s(-1) and an electron mobility of 0.03 cm(2) V-1 s(-1).

引用

页码：6725 / 6727

页数：3

共 25 条

[1]

Low-Voltage Organic Field Effect Transistors with a 2-Tridecyl[1]benzothieno[3,2-b][1]benzothiophene Semiconductor Layer [J].

Amin, Atefeh Y. ;

Khassanov, Artoem ;

Reuter, Knud ;

Meyer-Friedrichsen, Timo ;

Halik, Marcus .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (40) :16548-16550

[2]

[Anonymous], VAMP 11 0

[3]

Functionalized pentacene: Improved electronic properties from control of solid-state order [J].

Anthony, JE ;

Brooks, JS ;

Eaton, DL ;

Parkin, SR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (38) :9482-9483

[4]

The larger acenes: Versatile organic semiconductors [J].

Anthony, John E. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (03) :452-483

[5]

Suppression of charge carrier tunneling through organic self-assembled monolayers [J].

Boulas, C ;

Davidovits, JV ;

Rondelez, F ;

Vuillaume, D .

PHYSICAL REVIEW LETTERS, 1996, 76 (25) :4797-4800

[6]

General observation of n-type field-effect behaviour in organic semiconductors [J].

Chua, LL ;

Zaumseil, J ;

Chang, JF ;

Ou, ECW ;

Ho, PKH ;

Sirringhaus, H ;

Friend, RH .

NATURE, 2005, 434 (7030) :194-199

[7]

Clark T., 2011, EMPIRE 12

[8]

THE DEVELOPMENT AND USE OF QUANTUM-MECHANICAL MOLECULAR-MODELS .76. AM1 - A NEW GENERAL-PURPOSE QUANTUM-MECHANICAL MOLECULAR-MODEL [J].

DEWAR, MJS ;

ZOEBISCH, EG ;

HEALY, EF ;

STEWART, JJP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (13) :3902-3909

[9]

Semiempirical UNO-CAS and UNO-CI: Method and Applications in Nanoelectronics [J].

Dral, Pavlo O. ;

Clark, Timothy .

JOURNAL OF PHYSICAL CHEMISTRY A, 2011, 115 (41) :11303-11312

[10]

Local molecular properties and their use in predicting reactivity [J].

Ehresmann, B ;

Martin, B ;

Horn, AHC ;

Clark, T .

JOURNAL OF MOLECULAR MODELING, 2003, 9 (05) :342-347

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