Manganese complexes of 1,3,5-triaza-7-phosphaadamantane (PTA): The first nitrogen-bound transition-metal complex of PTA

被引：52

作者：

Frost, BJ ^{[1
]}

Bautista, CM ^{[1
]}

Huang, RC ^{[1
]}

Shearer, J ^{[1
]}

机构：

[1] Univ Nevada, Dept Chem, Reno, NV 89557 USA

来源：

INORGANIC CHEMISTRY | 2006年 / 45卷 / 09期

关键词：

D O I：

10.1021/ic060322p

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The structures of two manganese(II) complexes of 1,3,5-triaza-7-phosphaadamantane (PTA) reveal the first transition-metal complexes of PTA in which the metal preferentially coordinates to a nitrogen and not the phosphorus of PTA. The coordination environment about the manganese was probed using X-ray crystallography (solid state) and EXAFS spectroscopy (solution).

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页码：3481 / 3483

页数：3

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