Resin-Immobilized CuO and Cu Nanocomposites for Alcohol Oxidation

被引：51

作者：

Pande, Surojit ^{[1
]}

Saha, Arindam ^{[1
]}

Jana, Subhra ^{[1
]}

Sarkar, Sougata ^{[1
]}

Basu, Mrinmoyee ^{[1
]}

Pradhan, Mukul ^{[1
]}

Sinha, Arun Kumar ^{[1
]}

Saha, Sandip ^{[1
]}

Pal, Anjali ^{[1
]}

Pal, Tarasankar ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem & Civil Engn, Kharagpur 721302, W Bengal, India

来源：

ORGANIC LETTERS | 2008年 / 10卷 / 22期

关键词：

D O I：

10.1021/ol802040x

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Resin immobilized stable, spherical CuO nanoparticles prepared in the presence of cyclodextrin (CD) act as catalysts for liquid phase alcohol oxidation in air. The catalytic activity of the CuO nanocomposites and its green chemistry approach make it superior to the related resinbound Cu(0) nanocomposite. The effect of alcohol chain length and electron-donating or -withdrawing groups influence product yield. The nanocomposites exhibit good reusability, simple workup procedure, and a straightforward approach to aldehyde formation.

引用

页码：5179 / 5181

页数：3

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