Utilization of an industrial feedstock without separation - Ruthenium-catalysed hydrocarboxylation of propadiene and propyne

被引：9

作者：

Bruneau, C ^{[1
]}

Neveux-Duflos, M ^{[1
]}

Dixneuf, PH ^{[1
]}

机构：

[1] Univ Rennes 1, CNRS, UMR 6509, F-35042 Rennes, France

来源：

GREEN CHEMISTRY | 1999年 / 1卷 / 04期

关键词：

D O I：

10.1039/a903452h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of carboxylic acids with propadiene or propyne catalysed by [Ru(mu-O2CH)(CO)(2)(PPh3)](2) affords isopropenyl esters via regioselective addition of the carboxylate to the central carbon atom of the allene.

引用

页码：183 / 185

页数：3

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