Selective Methylation of Amines with Carbon Dioxide and H2

被引：242

作者：

Li, Yuehui ^{[1
]}

Sorribes, Ivan ^{[1
]}

Yan, Tao ^{[1
]}

Junge, Kathrin ^{[1
]}

Beller, Matthias ^{[1
]}

机构：

[1] Leibniz Inst Katalyse eV, D-18059 Rostock, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 46期

关键词：

homogeneous catalysis; hydrogen; methylation; reduction; ruthenium; HOMOGENEOUS CATALYTIC-HYDROGENATION; IRIDIUM CATALYST; REDUCTION; CO2; METHANOL; TRANSFORMATION; BICARBONATES; DERIVATIVES; ALCOHOLS; AMIDES;

D O I：

10.1002/anie.201306850

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Put a label on it: Carbon dioxide with H2 is shown to be an efficient and selective methylation reagent for aromatic and aliphatic amines (see scheme; acac=acetylacetonate, triphos = 1,1,1- tris(diphenylphosphanylmethyl)ethane). A variety of functionalized amines including 13C-labelled drugs were obtained with good yields and functional-group tolerance. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：12156 / 12160

页数：5

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