Large piezoelectric effect in lead-free Ba(Zr0.2Ti0.8)O3-(Ba0.7Ca0.3)TiO3 films prepared by screen printing with solution infiltration process

被引:11
作者
Feng, Zuyong [1 ,2 ]
Shi, Dongqi [2 ]
Dou, Shixue [2 ]
Tang, Xingui [1 ]
Hu, Yihua [1 ]
机构
[1] Guangdong Univ Technol, Sch Phys & Optoelect Engn, Guangzhou 510006, Guangdong, Peoples R China
[2] Univ Wollongong, Inst Superconducting & Elect Mat, N Wollongong, NSW 2500, Australia
基金
澳大利亚研究理事会;
关键词
Ferroelectric films; Lead-free; Solution infiltration; Dielectrics and piezoelectricity; THICK-FILMS; LIQUID-PHASE;
D O I
10.1016/j.tsf.2012.11.066
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
High-quality piezoelectric Ba(Zr0.2Ti0.8)O-3-50(Ba0.7Ca0.3)TiO3 films with very dense and homogenous microstructure were fabricated using chemical solution infiltration into porous screen-printed films. The films with a thickness of 10 mu m exhibited high relative permittivity of 2380, low dielectric loss of 1.6% (at 10 kHz), large remanent polarization of 22 mu C/cm(2), and large longitudinal piezoelectric constant d(33) of 220 pC/N, which is even better than the case of lead-based piezoelectric films. The excellent electrical properties make the films a promising candidate for practical applications in lead-free microdevices such as piezoelectric microelectromechanical systems. (C) 2012 Elsevier B. V. All rights reserved.
引用
收藏
页码:110 / 113
页数:4
相关论文
共 14 条
[1]   Electrical properties of Li doped sodium potassium niobate thick films prepared by a tape casting process [J].
Fu, Fang ;
Shen, Bo ;
Zhai, Jiwei ;
Xu, Zhengkui ;
Yao, Xi .
JOURNAL OF ALLOYS AND COMPOUNDS, 2011, 509 (25) :7130-7133
[2]   DENSIFICATION DURING SINTERING IN THE PRESENCE OF A LIQUID PHASE .2. EXPERIMENTAL [J].
KINGERY, WD ;
NARASIMHAN, MD .
JOURNAL OF APPLIED PHYSICS, 1959, 30 (03) :307-310
[3]   Theoretical analysis of liquid-phase sintering: Pore filling theory [J].
Lee, SM ;
Kang, SJL .
ACTA MATERIALIA, 1998, 46 (09) :3191-3202
[4]   Large Piezoelectric Effect in Pb-Free Ceramics [J].
Liu, Wenfeng ;
Ren, Xiaobing .
PHYSICAL REVIEW LETTERS, 2009, 103 (25)
[5]   Fabrication and ferroelectric properties of highly dense lead-free piezoelectric (K0.5Na0.5)NbO3 thick films by aerosol deposition [J].
Ryu, Jungho ;
Choi, Jong-Jin ;
Hahn, Byung-Dong ;
Park, Dong-Soo ;
Yoon, Woon-Ha ;
Kim, Ki-Hoon .
APPLIED PHYSICS LETTERS, 2007, 90 (15)
[6]   Ferroelectric and piezoelectric properties of 0.948(K0.5Na0.5)NbO3-0.052LiSbO3 lead-free piezoelectric thick film by aerosol deposition [J].
Ryu, Jungho ;
Choi, Jong-Jin ;
Hahn, Byung-Dong ;
Park, Dong-Soo ;
Yoon, Woon-Ha .
APPLIED PHYSICS LETTERS, 2008, 92 (01)
[7]  
Sun X.M., 2009, SCRIPTA MATER, V61, P536
[8]   Thick-film piezoceramics and devices [J].
Torah, R. N. ;
Beeby, S. P. ;
Tudor, M. J. ;
White, N. M. .
JOURNAL OF ELECTROCERAMICS, 2007, 19 (01) :97-112
[9]   Experimental investigation into the effect of substrate clamping on the piezoelectric behaviour of thick-film PZT elements [J].
Torah, RN ;
Beeby, SP ;
White, NM .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2004, 37 (07) :1074-1078
[10]   Enhanced piezoelectric properties of (Ba0.85Ca0.15)(Ti0.9Zr0.1)O3 lead-free ceramics by optimizing calcination and sintering temperature [J].
Wang, Pan ;
Li, Yongxiang ;
Lu, Yiqing .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2011, 31 (11) :2005-2012