The solid-phase reaction of [60]fullerene: Novel addition of organozinc reagents

被引：64

作者：

Wang, GW

Murata, Y

Komatsu, K

Wan, TSM

机构：

[1] KYOTO UNIV,INST CHEM RES,UJI,KYOTO 611,JAPAN

[2] HONG KONG UNIV SCI & TECHNOL,DEPT CHEM,KOWLOON,HONG KONG

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 17期

关键词：

D O I：

10.1039/cc9960002059

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of ethyl bromoacetate and zinc with [60]fullerene in the absence. of any solvent, followed by quenching with acid affords 1-ethoxycarbonylmethyl-1,2-dihydro[60]fullerene along with other minor byproducts including 1,4-bis(ethoxycarbonylmethyl)-1,4-dihydro[60]fullerene; a detailed reaction mechanism is proposed.

引用

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页码：2059 / 2060

页数：2

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