Spectroscopic Evidence for the Structure Directing Role of the Solvent in the Synthesis of Two Iron Carboxylates

被引：23

作者：

Celic, Tadeja Birsa ^{[1
,2
]}

Rangus, Mojca ^{[1
,2
]}

Lazar, Karoly ^{[3
]}

Kaucic, Venceslav ^{[1
,2
]}

Logar, Natasa Zabukovec ^{[1
,2
]}

机构：

[1] Natl Inst Chem, Lab Inorgan Chem & Technol, Ljubljana 1000, Slovenia

[2] Ctr Excellence Low Carbon Technol, Ljubljana 1000, Slovenia

[3] HAS, Inst Isotopes, Energy Res Ctr, H-1525 Budapest, Hungary

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 50期

关键词：

crystallization; EXFAS spectroscopy; metal-organic frameworks; Moessbauer spectroscopy; METAL-ORGANIC FRAMEWORKS; X-RAY-SCATTERING; COORDINATION POLYMERS; HIGH-THROUGHPUT; TIME; CRYSTALLIZATION; DIFFRACTION; TOPOLOGIES; LIGAND; EXAFS;

D O I：

10.1002/anie.201204573

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Crystal engineering: The synthesis of the known compounds MIL-100(Fe) and MIL-45(Fe) is characterized by spectroscopy. The products are obtained under identical conditions by varying the solvent from pure water to a mixture of water and acetone. The starting solution, the gel, and the final reaction product were characterized by X-ray absorption spectroscopy (see picture). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：12490 / 12494

页数：5

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