Kinetics of the reactions of IO with HO2 and O(3P)

被引：16

作者：

Canosa-Mas, CE ^{[1
]}

Flugge, ML ^{[1
]}

Shah, D ^{[1
]}

Vipond, A ^{[1
]}

Wayne, RP ^{[1
]}

机构：

[1] Univ Oxford, Phys & Theoret Chem Lab, Oxford OX1 3QZ, England

来源：

JOURNAL OF ATMOSPHERIC CHEMISTRY | 1999年 / 34卷 / 01期

关键词：

iodine; IO; HO2; O(P-3); discharge-flow; resonance fluorescence;

D O I：

10.1023/A:1006262306459

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

A discharge-flow tube coupled with resonance fluorescence and chemiluminescence detection has been used to investigate the reactions IO + HO2 --> products (1) and IO + O(P-3) --> I + O-2 (2), at T = 296 + 1 K and P = 1.7 - 2 Torr. The rate constants k(1) and k(2) have been found to be (7.1 + 1.6) x 10(-11) cm(3) molecule(-1) s(-1) and (1.35 +/- 0.15) x 10(-10) cm(3) molecule(-1) s(-1), respectively.

引用

页码：153 / 162

页数：10

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