Copolymerization of isoprene with nonconjugated α,ω-dienes using a single component samarocene catalyst

被引：35

作者：

Bonnet, F ^{[1
]}

Visseaux, M ^{[1
]}

Barbier-Baudry, D ^{[1
]}

Dormond, A ^{[1
]}

机构：

[1] Univ Bourgogne, UMR 5632 CNRS, Lab Synthese & Electrosynthese Organomet, F-21078 Dijon, France

来源：

MACROMOLECULES | 2002年 / 35卷 / 04期

关键词：

D O I：

10.1021/ma011437+

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Isoprene with hexa-1,5-diene and octa-1,7-diene αω-dienes was copolymerized. The molecular structure of the macromolecular chain was established on the basis of nunclear magnetic resonance (NMR) analysis. The thermal properties of the copolymers were determined. Isoprene/α-olefin/α,ω-diene terpolymers were also obtained.

引用

页码：1143 / 1145

页数：3

共 36 条

[1]

BAIRD MC, Patent No. 004061

[2] Organolanthanides, catalysts for specific olefin-diene copolymerization: access to new materials [J].

Barbier-Baudry, D ;

Bonnet, F ;

Dormond, A ;

Hafid, A ;

Nyassi, A ;

Visseaux, M .

JOURNAL OF ALLOYS AND COMPOUNDS, 2001, 323 :592-596

[3] Organolanthanides as single component homogeneous catalysts for isoprene-hex-1-ene co-polymerisation [J].

Barbier-Baudry, D ;

Dormond, A ;

Desmurs, P .

COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE C-CHIMIE, 1999, 2 (7-8) :375-378

[4]

BARBIERBAUDRY D, 2001, IN PRESS J ORGANOMET

[5] First synthesis of poly(ethene-co-1,3-butadiene) with neodymocene catalysts [J].

Barbotin, F ;

Monteil, V ;

Llauro, MF ;

Boisson, C ;

Spitz, R .

MACROMOLECULES, 2000, 33 (23) :8521-8523

[6]

Baudry-Barbier D, 1998, EUR J INORG CHEM, P1721

[7] Copolymerization of polar monomers with olefins using transition-metal complexes [J].

Boffa, LS ;

Novak, BM .

CHEMICAL REVIEWS, 2000, 100 (04) :1479-1493

[8] Kinetics of the polymerization of isoprene with isopropoxyneodymium dichloride/triethylaluminium binary lanthanide catalyst system [J].

Cai, XP ;

Gong, Z ;

Wang, FS ;

Zhu, XH .

MACROMOLECULAR CHEMISTRY AND PHYSICS, 1996, 197 (04) :1449-1458

[9] Precise control of polyolefin stereochemistry using single-site metal catalysts [J].

Coates, GW .

CHEMICAL REVIEWS, 2000, 100 (04) :1223-1252

[10] Preliminary investigations on polymerization catalysts composed of lanthanocene and methylaluminoxane [J].

Cui, LQ ;

Ba, XW ;

Teng, HX ;

Ying, LQ ;

Li, KC ;

Jin, YT .

POLYMER BULLETIN, 1998, 40 (06) :729-734

← 1 2 3 4 →