Expanding the chemistry of U3+ reducing agents

被引：96

作者：

Evans, WJ ^{[1
]}

Kozimor, SA ^{[1
]}

机构：

[1] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA

来源：

COORDINATION CHEMISTRY REVIEWS | 2006年 / 250卷 / 7-8期

基金：

美国国家科学基金会;

关键词：

uranium; reduction; sterically induced reduction; multi-electron reduction; actinicle; organometaltic; cyclopentadienyl;

D O I：

10.1016/j.ccr.2006.01.017

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The U3+ ion offers many opportunities for developing new actinide reaction chemistry. This review surveys the traditional non-aqueous U3+ reduction chemistry in the literature and summarizes recent attempts to combine U3+ reduction with ligand-based reductions to achieve multi-electron reduction with complexes of this ion. The purpose of this analysis is to better identify new possibilities for further expansion of the reduction chemistry of U3+. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：911 / 935

页数：25

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