Alkynylxenon(II) fluorides

被引：9

作者：

Schmidt, H ^{[1
]}

Scherer, H ^{[1
]}

Tyrra, W ^{[1
]}

Hahn, J ^{[1
]}

Naumann, D ^{[1
]}

机构：

[1] Univ Cologne, Inst Anorgan Chem, D-50939 Cologne, Germany

来源：

INORGANIC CHEMISTRY | 2004年 / 43卷 / 06期

关键词：

D O I：

10.1021/ic035394k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Alkynylxenon(II) fluorides, RC=-CXeF, have been prepared from the reactions of the corresponding trimethyl(alkynyl)silanes, Me-3- SiCdropCR, and XeF2 in the presence of [NMe4]F in common organic solvents at low temperature. The existence of the linear unit CdropC-Xe-F was proved for PhCdropCXeF by the F-19-C-13 NMR correlation method using the HMBC pulse sequence.

引用

页码：1837 / 1839

页数：3

共 12 条

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