Dynamic covalent self-assembled macrocycles prepared from 2-formyl-aryl-boronic acids and 1,2-amino alcohols

被引：47

作者：

Galbraith, Ewan ^{[1
]}

Kelly, Andrew M. ^{[1
]}

Fossey, John S. ^{[1
]}

Kociok-Koehn, Gabriele ^{[1
]}

Davidson, Matthew G. ^{[1
]}

Bull, Steven D. ^{[1
]}

James, Tony D. ^{[1
]}

机构：

[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

来源：

NEW JOURNAL OF CHEMISTRY | 2009年 / 33卷 / 01期

基金：

英国工程与自然科学研究理事会;

关键词：

NMR ANALYSIS; ENANTIOMERIC PURITY; BORON MACROCYCLES; SIMPLE PROTOCOLS; SALEN; RECEPTORS; COMPLEXES;

D O I：

10.1039/b815138e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of 2-formyl-aryl-boronic acids with 1,2-amino alcohols results in dynamic covalent self assembly to quantitatively afford tetracyclic macrocyclic Schiff base boracycles containing bridging boron-oxygen-boron functionality.

引用

页码：181 / 185

页数：5

共 37 条

[1] Enantiopure pseudo-C3-symmetric titanium alkoxide with propeller-like chirality [J].

Axe, Philip ;

Bull, Steven D. ;

Davidson, Matthew G. ;

Gilfillan, Carly J. ;

Jones, Matthew D. ;

Robinson, Diane E. J. E. ;

Turner, Luke E. ;

Mitchell, William L. .

ORGANIC LETTERS, 2007, 9 (02) :223-226

[2] Boron macrocycles having a calix-like shape.: Synthesis, characterization, X-ray analysis, and inclusion properties [J].

Barba, V ;

Villamil, R ;

Luna, R ;

Godoy-Alcántar, C ;

Hopfl, H ;

Beltran, HI ;

Zamudio-Rivera, LS ;

Santillan, R ;

Farfán, N .

INORGANIC CHEMISTRY, 2006, 45 (06) :2553-2561

[3] Boron-nitrogen macrocycles:: a new generation of calix[3]arenes [J].

Barba, V ;

Höpfl, H ;

Farfán, N ;

Santillan, R ;

Beltran, HI ;

Zamudio-Rivera, LS .

CHEMICAL COMMUNICATIONS, 2004, (24) :2834-2835

[4] New boron macrocycles based on self-assembly of Schiff bases [J].

Barba, V ;

Gallegos, E ;

Santillan, R ;

Farfán, N .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 622 (1-2) :259-264

[5] Direct synthesis of polymacrocyclic boron compounds. A convenient method for the synthesis of hemicarcerands [J].

Barba, Victor ;

Betanzos, Isabel .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2007, 692 (22) :4903-4908

[6] Binary and ternary phenylboronic acid complexes with saccharides and Lewis bases [J].

Bosch, LI ;

Fyles, TM ;

James, TD .

TETRAHEDRON, 2004, 60 (49) :11175-11190

[7] Multicomponent assembly of boronic acid based macrocycles and cages [J].

Christinat, Nicolas ;

Scopelliti, Rosario ;

Severin, Kay .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (10) :1848-1852

[8] Multicomponent assembly of boron-based dendritic nanostructures [J].

Christinat, Nicolas ;

Scopelliti, Rosario ;

Severin, Kay .

JOURNAL OF ORGANIC CHEMISTRY, 2007, 72 (06) :2192-2200

[9]

Davis AP, 2005, FUNCTIONAL SYNTHETIC RECEPTORS, P45, DOI 10.1002/352760572X.ch2

[10] New perspectives for boronic esters in macrocyclic chemistry [J].

Farfán, N ;

Höpfl, H ;

Barba, V ;

Ochoa, ME ;

Santillan, R ;

Gómez, E ;

Gutiérrez, A .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 581 (1-2) :70-81

← 1 2 3 4 →