New boron macrocycles based on self-assembly of Schiff bases

被引：50

作者：

Barba, V ^{[1
]}

Gallegos, E ^{[1
]}

Santillan, R ^{[1
]}

Farfán, N ^{[1
]}

机构：

[1] Inst Politecn Nacl, Ctr Invest & Estudios Avanzados, Dept Quim, Mexico City 07000, DF, Mexico

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2001年 / 622卷 / 1-2期

关键词：

Schiff bases; imines; macrocyclic boronates; self-assembly;

D O I：

10.1016/S0022-328X(00)00929-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In order to investigate the formation of macrocyclic boronates, we carried out the reaction of 3-aminophenyl boronic acid with salicylaldehyde, 2-hydroxyacetophenone and 2-hydroxybenzophenone. In all cases, macrocyclic structures were formed and the X-ray crystallographic study of the trimeric complex derived from 2-hydroxyacetophenone showed that the macrocyclic system is asymmetric. (C) 2001 Published by Elsevier Science B.V. All rights reserved.

引用

页码：259 / 264

页数：6

共 33 条

[1] MACROCYCLIC AND MACROACYCLIC COMPARTMENTAL SCHIFF-BASES - SYNTHESIS, CHARACTERIZATION, X-RAY STRUCTURE AND INTERACTION WITH METAL-IONS [J].

AGUIARI, A ;

BULLITA, E ;

CASELLATO, U ;

GUERRIERO, P ;

TAMBURINI, S ;

VIGATO, PA .

INORGANICA CHIMICA ACTA, 1992, 202 (02) :157-171

[2] DINUCLEATING MACROCYCLIC SCHIFF-BASES DERIVED FROM THIOPHENE AND THEIR METAL-COMPLEXES - THE CRYSTAL-STRUCTURES OF A FREE MACROCYCLE AND OF A DISILVER COMPLEX [J].

BAILEY, NA ;

EDDY, MM ;

FENTON, DE ;

MOSS, S ;

MUKHOPADHYAY, A ;

JONES, G .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (10) :2281-2288

[3] Two new complexes of phenylboronic acid with N-salicylidene-4-aminobutanol [J].

Barba, V ;

Cuahutle, D ;

Ochoa, ME ;

Santillan, R ;

Farfán, N .

INORGANICA CHIMICA ACTA, 2000, 303 (01) :7-11

[4] Synthesis and molecular structures of dimeric boron compounds [J].

Barba, V ;

Luna, R ;

Castillo, D ;

Santillan, R ;

Farfán, N .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2000, 604 (02) :273-282

[5] DIALDEHYDE PLUS DIAMINE - POLYMER OR MACROCYCLE [J].

BRUNNER, H ;

SCHIESSLING, H .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1994, 33 (01) :125-126

[6] New perspectives for boronic esters in macrocyclic chemistry [J].

Farfán, N ;

Höpfl, H ;

Barba, V ;

Ochoa, ME ;

Santillan, R ;

Gómez, E ;

Gutiérrez, A .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 581 (1-2) :70-81

[7] THROUGH-BOND MODULATION OF N-]B RING FORMATION SHOWN BY NMR AND X-RAY-DIFFRACTION STUDIES OF BORATE DERIVATIVES OF PYRIDYL ALCOHOLS [J].

FARFAN, N ;

CASTILLO, D ;

JOSEPHNATHAN, P ;

CONTRERAS, R ;

VONSZENTPALY, L .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1992, (04) :527-532

[8]

FARFAN N, 1999, NEWS, V7, P3

[9] The [Mn2(2-OHsalpn)2]2-,1-,0 system:: An efficient functional model for the reactivity and inactivation of the manganese catalases [J].

Gelasco, A ;

Bensiek, S ;

Pecoraro, VL .

INORGANIC CHEMISTRY, 1998, 37 (13) :3301-3309

[10] FROM MONONUCLEAR TO POLYNUCLEAR MACROCYCLIC OR MACROACYCLIC COMPLEXES [J].

GUERRIERO, P ;

TAMBURINI, S ;

VIGATO, PA .

COORDINATION CHEMISTRY REVIEWS, 1995, 139 :17-243

← 1 2 3 4 →