A supramolecular approach to the crystallization of polynuclear aqua ions: Structure and magnetism of an 18-crown-6 adduct of bis(mu-hydroxo)octaaquadichromium(III) mesitylene-2-sulfonate trihydrate

被引：20

作者：

Drljaca, A ^{[1
]}

Hockless, DCR ^{[1
]}

Moubaraki, B ^{[1
]}

Murray, KS ^{[1
]}

Spiccia, L ^{[1
]}

机构：

[1] MONASH UNIV,DEPT CHEM,CLAYTON,VIC 3168,AUSTRALIA

来源：

INORGANIC CHEMISTRY | 1997年 / 36卷 / 10期

关键词：

D O I：

10.1021/ic9614125

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A supramolecular approach to the crystallization of polynuclear aqua ions has been developed which utilizes the ability of the donor atoms of macrocyclic ligands, such as 18-crown-6, to hydrogen-bond to coordinated water molecules, thereby modifying the 3D II-bonding network that surrounds such ions in aqueous solution. The synthesis, X-ray structure, and magnetic properties of [Cr-2(mu-OH)(2)(H2O)(8)][(H3C)(3)C6H2SO3](4) . C12H24O6 . 3H(2)O are reported.

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页码：1988 / &

页数：3

相关论文

共 22 条

[1] NOVEL CUBANE-TYPE MOLYBDENUM TIN CLUSTER COMPLEXES [(H2O)9MO3S4SNS4MO3(H2O)9]8+ AND MO3SNS4(AQ)6+ [J].

AKASHI, H ;

SHIBAHARA, T .

INORGANIC CHEMISTRY, 1989, 28 (15) :2906-2907

[2] LONG-DISTANCE MAGNETIC EXCHANGE BETWEEN CHROMIUM(III) ATOMS BRIDGED BY H3O2-LIGANDS [J].

ARDON, M ;

BINO, A ;

MICHELSEN, K ;

PEDERSEN, E .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (19) :5855-5856

[3] DEPENDENCE OF THE MAGNETIC SUPEREXCHANGE ON THE CR...CR DISTANCE IN DINUCLEAR CHROMIUM(II) COMPLEXES [J].

BOSSEK, U ;

WIEGHARDT, K ;

NUBER, B ;

WEISS, J .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (09) :1055-1057

[4] HYDROLYTIC POLYMERIZATION OF RHODIUM(III) .1. PREPARATION, SOLUTION STUDIES, AND X-RAY STRUCTURE OF THE DOUBLY BRIDGED DIMER [(H2O)4RH(MU-OH)2RH(OH2)4](DMTOS)4.8H2O [J].

CERVINI, R ;

FALLON, GD ;

SPICCIA, L .

INORGANIC CHEMISTRY, 1991, 30 (04) :831-836

[5] SYNTHESIS AND X-RAY STRUCTURE OF A CHROMIUM(III)-RHODIUM(III) HETEROMETALLIC HYDROLYTIC DIMER - [(H2O)4RH(MU-OH)2CR(OH2)4](ME3C6H2SO3)4.4H2O [J].

CRIMP, SJ ;

FALLON, GD ;

SPICCIA, L .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (02) :197-198

[6]

CRIMP SJ, 1994, UNPUB

[7] SUPRAMOLECULAR SYNTHONS IN CRYSTAL ENGINEERING - A NEW ORGANIC-SYNTHESIS [J].

DESIRAJU, GR .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (21) :2311-2327

[8]

DRLJACA A, 1994, INORG CHEM, V27, P2660

[9] A NOVEL CORRELATION BETWEEN MAGNETISM AND STRUCTURAL PARAMETERS IN SUPEREXCHANGE COUPLED CHROMIUM(III) DIMERS [J].

GLERUP, J ;

HODGSON, DJ ;

PEDERSEN, E .

ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1983, 37 (02) :161-164

[10] MAGNETIC EXCHANGE THROUGH HYDROGEN-BONDS - STRUCTURAL AND MAGNETIC CHARACTERIZATION OF CIS-HYDROXOAQUACHROMIUM(III) COMPLEXES OF TETRADENTATE AND MONODENTATE LIGANDS [J].

GOODSON, PA ;

GLERUP, J ;

HODGSON, DJ ;

MICHELSEN, K ;

RYCHLEWSKA, U .

INORGANIC CHEMISTRY, 1994, 33 (02) :359-366