ONE-POT TANDEM SYNTHESIS OF β-TRIMETHYLSILYLOXY THIOESTERS FROM THIOACIDS, EPOXIDES, AND HMDS CATALYZED BY SILICA GEL UNDER SOLVENT-FREE CONDITIONS

被引：4

作者：

Abbasi, Mohammad ^{[1
]}

机构：

[1] Persian Gulf Univ, Dept Chem, Fac Sci, Bushehr 75169, Iran

来源：

SYNTHETIC COMMUNICATIONS | 2013年 / 43卷 / 13期

关键词：

Epoxide; hexamethyl disilazane; silica gel; solvent-free; thioacid; thioester; DODECYL-SULFATE SDS; MICELLAR-SOLUTION; EFFICIENT; THIOLESTERS; REAGENTS; OXIRANES;

D O I：

10.1080/00397911.2012.667183

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A procedure for one-pot preparation of beta-trimethylsilyloxy thioesters from epoxides, thioacids, and hexamethyl disilazane (HMDS) in the presence of silica gel under solvent-free condition was developed. The desired silylated products were isolated in good to excellent yields after silica-gel column chromatography. Supplemental materials are available for this article. Go to the publisher's online edition of Synthetic Communications (R) to view the free supplemental file.

引用

页码：1759 / 1765

页数：7

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