Polymorphism, what it is and how to identify it: a systematic review

被引：150

作者：

Brog, Jean-Pierre ^{[1
]}

Chanez, Claire-Lise ^{[1
]}

Crochet, Aurelien ^{[1
]}

Fromm, Katharina M. ^{[1
]}

机构：

[1] Fribourg Ctr Nanomat FriMat, Dept Chem, CH-1700 Fribourg, Switzerland

来源：

RSC ADVANCES | 2013年 / 3卷 / 38期

关键词：

CRYSTAL-STRUCTURE PREDICTION; SMALL ORGANIC-MOLECULES; PARACETAMOL FORM-III; X-RAY-DIFFRACTION; COORDINATION POLYMER; PHASE-TRANSITION; BEHAVIOR; ASPIRIN; 2,4,6-TRINITROTOLUENE; RITONAVIR;

D O I：

10.1039/c3ra41559g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This review on polymorphism is a personal, non-comprehensive view on the field of polymorphism - a term which is often misused. Indeed, the discussion about polymorphism and related terms is still ongoing in the area of crystal engineering. This is why we felt it timely to look into the historical development of its definition and to delimit it. A short introduction to thermodynamic aspects and characterization methods of polymorphs is given. One chapter is then dedicated to polymorphism of elements and inorganic compounds, before discussing the term for organic and organo-metallic compounds. Chosen examples are given each time to illustrate the cases of polymorphism. In the end, the conclusion yields three flow schemes useful in determining polymorphism for each compound class.

引用

页码：16905 / 16931

页数：27

共 154 条

[11]

2-#

[12]

Bernstein J., 2020, Polymorphism in molecular crystals 2e, Vvol. 30

[13]

Berzelius J., JAHRES BERICHT, V1832, P44

[14]

Berzelius J., 1841, JAHRES BERICHT, V20, P7

[15] Dimer or catemer? Low-energy crystal packings for small carboxylic acids [J].

Beyer, T ;

Price, SL .

JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (12) :2647-2655

[16] Possible links between long-term geomagnetic variations and whole-mantle convection processes (vol 5, pg 526, 2012) [J].

Biggin, A. J. ;

Steinberger, B. ;

Aubert, J. ;

Suttie, N. ;

Holme, R. ;

Torsvik, T. H. ;

van der Meer, D. G. ;

van Hinsbergen, D. J. J. .

NATURE GEOSCIENCE, 2012, 5 (09) :674-674

[17]

Bond AD, 2007, ANGEW CHEM INT EDIT, V46, P618, DOI 10.1002/anie.200603373

[18] On the polymorphism of aspirin [J].

Bond, Andrew D. ;

Boese, Roland ;

Desiraju, Gautam R. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (04) :615-617

[19] Polymorphism of molecular organometallic crystals.: A third form of the supramolecular hydrogen-bonded dimer {[FeII(η5-C5H4COOH)2]}2 [J].

Braga, D ;

Polito, M ;

D'Addario, D ;

Grepioni, F .

CRYSTAL GROWTH & DESIGN, 2004, 4 (06) :1109-1112

[20] A solid-gas route to polymorph conversion in crystalline [FeII(η5-C5H4COOH)2].: A diffraction and solid-state NMR study [J].

Braga, Dario ;

Grepioni, Fabrizia ;

Polito, Marco ;

Chierotti, Michele R. ;

Ellena, Silvano ;

Gobetto, Roberto .

ORGANOMETALLICS, 2006, 25 (19) :4627-4633

← 1 2 3 4 5 6 7 8 9 10 →