Effect of the nature of the metal on the breathing steps in MOFs with dynamic frameworks

被引：289

作者：

Millange, Franck ^{[1
]}

Guillou, Nathalie ^{[1
]}

Walton, Richard I. ^{[2
]}

Greneche, Jean-Marc ^{[3
]}

Margiolaki, Irene ^{[4
]}

Fereya, Gerard ^{[1
]}

机构：

[1] Univ Versailles St Quentin Yvelines, Inst Lavoisier, CNRS UMR 8180, F-78035 Versailles, France

[2] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England

[3] Univ Maine, CNRS UMR 6087, Lab Phys Etat Condense, F-72085 Le Mans, France

[4] European Synchrotron Radiat Facil, Mat Sci Grp, ID31, F-38043 Grenoble, France

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 39期

关键词：

D O I：

10.1039/b809419e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The thermal behaviour of the nanoporous iron(III) terephthalate MIL-53 is in stark contrast to its chromium and aluminium analogues which show an expansion of the cell during dehydration; with iron, reversible dehydration occurs via evolution of the structure through a highly distorted metastable anhydrous phase to a more regular phase above 423 K in which pore volume remains approximately constant.

引用

页码：4732 / 4734

页数：3

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