Highly stable a-Si:H films deposited by using multi-hollow plasma chemical vapor deposition

被引:50
作者
Koga, K [1 ]
Inoue, T [1 ]
Bando, K [1 ]
Iwashita, S [1 ]
Shiratani, M [1 ]
Watanabe, Y [1 ]
机构
[1] Kyushu Univ, Dept Elect, Fukuoka 8128581, Japan
来源
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS | 2005年 / 44卷 / 46-49期
关键词
hydrogenated amorphous silicon films; light-induced degradation; Staebler-Wronski effects; plasma CVD; clusters; defect density;
D O I
10.1143/JJAP.44.L1430
中图分类号
O59 [应用物理学];
学科分类号
摘要
Hydrogenated amorphous silicon (a-Si:H) films of high stability against light exposure have been deposited by using a newly developed multi-hollow plasma chemical vapor deposition (CVD) method. Films deposited in the upstream region in the multi-hollow plasma CVD reactor are a-Si:H films without incorporating a-Si:H nano-particles (clusters), while those in the downstream region are a-Si:H films with incorporating clusters. A-Si:H films without clusters have a low initial defect density of 5 x 10(15) cm(-3) and keep the value even after 100 h exposure of intense light intensity of 240 mW/cm(2), whereas a-Si:H films with clusters show a significant increase in defect density from its initial value of 5 x 10(15) cm(-3) to 2 x 10(16) cm(-3) after 100 h light exposure. These results indicate that suppression of clusters incorporated into films is the key to realizing highly stable a-Si:H films.
引用
收藏
页码:L1430 / L1432
页数:3
相关论文
共 11 条
[1]  
BRODSKY MH, 1977, PHYS REV B, V16, P3556, DOI 10.1103/PhysRevB.16.3556
[2]   Cluster-eliminating filter for depositing cluster-free a-Si:H films by plasma chemical vapor deposition -: art. no. 113501 [J].
Koga, K ;
Kaguchi, N ;
Bando, K ;
Shiratani, M ;
Watanabe, Y .
REVIEW OF SCIENTIFIC INSTRUMENTS, 2005, 76 (11) :1-4
[3]   In situ observation of nucleation and subsequent growth of clusters in silane radio frequency discharges [J].
Koga, K ;
Matsuoka, Y ;
Tanaka, K ;
Shiratani, M ;
Watanabe, Y .
APPLIED PHYSICS LETTERS, 2000, 77 (02) :196-198
[4]   Correlation between volume fraction of clusters incorporated into a-Si:H films and hydrogen content associated with Si-H2 bonds in the films [J].
Koga, K ;
Kaguchi, N ;
Shiratani, M ;
Watanabe, Y .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A, 2004, 22 (04) :1536-1539
[5]   Cluster-suppressed plasma chemical vapor deposition method for high quality hydrogenated amorphous silicon films [J].
Koga, K ;
Kai, M ;
Shiratani, M ;
Watanabe, Y ;
Shikatani, N .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS, 2002, 41 (2B) :L168-L170
[6]   Properties of a new a-Si:H-like material:: hydrogenated polymorphous silicon [J].
Longeaud, C ;
Kleider, JP ;
Cabarrocas, PRI ;
Hamma, S ;
Meaudre, R ;
Meaudre, M .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1998, 227 :96-99
[7]   Amorphous silicon solar cells deposited at high growth rate [J].
Nishimoto, T ;
Takai, M ;
Miyahara, H ;
Kondo, M ;
Matsuda, A .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2002, 299 :1116-1122
[8]   Metastability study and optimization of polymorphous silicon solar cells: the state-of-the-art [J].
Poissant, Y ;
Chatterjee, P ;
Cabarrocas, PRI .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2002, 299 :1173-1178
[9]  
Schropp R. E. I., 1998, AMORPHOUS MICROCRYST, P99
[10]   Effects of gas temperature gradient, pulse discharge modulation, and hydrogen dilution on particle growth in silane RF discharges [J].
Shiratani, M ;
Maeda, S ;
Koga, K ;
Watanabe, Y .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 2000, 39 (01) :287-293