Tridentate carbene CCC and CNC pincer palladium(II) complexes: Structure, fluxionality, and catalytic activity

被引:291
作者
Grundemann, S [1 ]
Albrecht, M [1 ]
Loch, JA [1 ]
Faller, JW [1 ]
Crabtree, RH [1 ]
机构
[1] Yale Univ, Dept Chem, New Haven, CT 06520 USA
关键词
D O I
10.1021/om010631h
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Air and thermally stable palladium(II) complexes of CNC and CCC bis-carbene pincer ligands have a twisted conformation and catalyze Heck olefination of activated aryl chlorides.
引用
收藏
页码:5485 / 5488
页数:4
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