Tridentate carbene CCC and CNC pincer palladium(II) complexes: Structure, fluxionality, and catalytic activity

被引：291

作者：

Grundemann, S ^{[1
]}

Albrecht, M ^{[1
]}

Loch, JA ^{[1
]}

Faller, JW ^{[1
]}

Crabtree, RH ^{[1
]}

机构：

[1] Yale Univ, Dept Chem, New Haven, CT 06520 USA

来源：

ORGANOMETALLICS | 2001年 / 20卷 / 25期

关键词：

D O I：

10.1021/om010631h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Air and thermally stable palladium(II) complexes of CNC and CCC bis-carbene pincer ligands have a twisted conformation and catalyze Heck olefination of activated aryl chlorides.

引用

页码：5485 / 5488

页数：4

共 33 条

[31] ELECTRONIC TUNING OF ARYLNICKEL(II) COMPLEXES BY PARA SUBSTITUTION OF THE TERDENTATE MONOANIONIC 2,6-BIS[(DIMETHYLAMINO)METHYL]PHENYL LIGAND [J].

VANDEKUIL, LA ;

LUITJES, H ;

GROVE, DM ;

ZWIKKER, JW ;

VANDERLINDEN, JGM ;

ROELOFSEN, AM ;

JENNESKENS, LW ;

DRENTH, W ;

VANKOTEN, G .

ORGANOMETALLICS, 1994, 13 (02) :468-477

[32] TUNING THE REACTIVITY OF METALS HELD IN A RIGID LIGAND ENVIRONMENT [J].

VANKOTEN, G .

PURE AND APPLIED CHEMISTRY, 1989, 61 (10) :1681-1694

[33] Synthesis and characterization of 14-electron cyclopentadienyl chromium(II) complexes containing a heterocyclic carbene ligand [J].

Voges, MH ;

Romming, C ;

Tilset, M .

ORGANOMETALLICS, 1999, 18 (04) :529-533

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