On Demand: The Singular rht Net, an Ideal Blueprint for the Construction of a Metal-Organic Framework (MOF) Platform

被引：117

作者：

Eubank, Jarrod F. ^{[2
]}

Nouar, Farid ^{[2
]}

Luebke, Ryan ^{[1
]}

Cairns, Amy J. ^{[1
]}

Wojtas, Lukasz ^{[2
]}

Alkordi, Mohamed ^{[1
]}

Bousquet, Till ^{[2
]}

Hight, Matthew R. ^{[2
]}

Eckert, Juergen ^{[2
]}

Embs, Jan P. ^{[3
]}

Georgiev, Peter A. ^{[4
]}

Eddaoudi, Mohamed ^{[1
,2
]}

机构：

[1] King Abdullah Univ Sci & Technol, KAUST Adv Membranes & Porous Mat Ctr, Thuwal 239556900, Saudi Arabia

[2] Univ S Florida, Dept Chem, Tampa, FL 33620 USA

[3] Paul Scherrer Inst, Neutron Scattering Lab, Villigen, Switzerland

[4] Univ Milan, Dept Struct Chem, I-20122 Milan, Italy

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 40期

关键词：

controlled porosity; hybrid materials; metal-organic frameworks; reticular chemistry; supermolecular building blocks; CARBON-DIOXIDE CAPTURE; POSTSYNTHETIC MODIFICATION; RETICULAR CHEMISTRY; BUILDING-BLOCKS; DESIGN; POLYHEDRA; DATABASE; UNITS; CO2;

D O I：

10.1002/anie.201201202

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The exceptional nature of the rht-MOF platform, based on a singular edge-transitive net (the only net for the combination of 3- and 24-connected nodes), makes it an ideal target in crystal chemistry. The high level of control indicates an unparalleled blueprint for isoreticular functional materials (without concern for interpenetration) for targeted applications. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：10099 / 10103

页数：5

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