Palladium catalysed cross-coupling of (fluoroarene)tricarbonylchromium(0) complexes

被引：73

作者：

Widdowson, DA ^{[1
]}

Wilhelm, RE ^{[1
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 21期

关键词：

D O I：

10.1039/a906256d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Fluoroarenetricarbonylchromium(0) complexes were found to undergo Suzuki reactions with arylboronic acids to form biaryltricarbonylchromium(0) complexes in the presence of trimethylphosphine/palladium dibenzylideneacetone and caesium carbonate or caesium fluoride.

引用

页码：2211 / 2212

页数：2

共 20 条

[1] Synthesis of 4-substituted phenylalanines by cross-coupling reactions: Extension of the methodology to aryl chlorides [J].

Firooznia, F ;

Gude, C ;

Chan, K ;

Satoh, Y .

TETRAHEDRON LETTERS, 1998, 39 (23) :3985-3988

[2] LITHIATION OF 2-FLUOROANISOLE(TRICARBONYL)CHROMIUM(O), 3-FLUOROANISOLE(TRICARBONYL)CHROMIUM(O), AND 4-FLUOROANISOLE(TRICARBONYL)CHROMIUM(O) COMPLEXES - A REVERSAL OF NORMAL REGIOCONTROL [J].

GILDAY, JP ;

WIDDOWSON, DA .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (16) :1235-1237

[3] FLUORINE DIRECTED LITHIATION IN TRICARBONYLARENECHROMIUM(O) COMPLEXES - THE REGIOSPECIFIC SYNTHESIS OF POLYSUBSTITUTED ARENES [J].

GILDAY, JP ;

WIDDOWSON, DA .

TETRAHEDRON LETTERS, 1986, 27 (45) :5525-5528

[4] Mechanistic studies on the aryl-aryl interchange reaction of ArPdL2I (L = triarylphosphine) complexes [J].

Goodson, FE ;

Wallow, TI ;

Novak, BM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (51) :12441-12453

[5] Cross-coupling reactions of aryl chlorides with organochlorosilanes: Highly effective methods for arylation or alkenylation of aryl chlorides [J].

Gouda, K ;

Hagiwara, E ;

Hatanaka, Y ;

Hiyama, T .

JOURNAL OF ORGANIC CHEMISTRY, 1996, 61 (21) :7232-7233

[6] Nucleophilic fluorine substitution of (eta(6)-fluoroarene) tricarbonylchromium complexes with dialkylphosphites [J].

Kirschke, K ;

Deutsch, J ;

Niclas, HJ .

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1996, 117 :293-298

[7]

Littke AF, 1998, ANGEW CHEM INT EDIT, V37, P3387, DOI 10.1002/(SICI)1521-3773(19981231)37:24<3387::AID-ANIE3387>3.0.CO

[8]

2-P

[9]

LITTLE AF, 1999, ANGEW CHEM INT EDIT, V38, P2413

[10]

LITVAK VV, 1984, ZH ORG KHIM+, V20, P753

← 1 2 →