Iron-Catalyzed Hydrosilylation of Esters

被引：101

作者：

Bezier, David ^{[1
]}

Venkanna, Gopaladasu T. ^{[1
]}

Castro, Luis C. Misal ^{[1
]}

Zheng, Jianxia ^{[1
]}

Roisnel, Thierry ^{[2
]}

Sortais, Jean-Baptiste ^{[1
]}

Darcel, Christophe ^{[1
]}

机构：

[1] Univ Rennes 1, Inst Sci Chim Rennes, Team Organometall Mat & Catalysis, CNRS,UR1,UMR 6226, F-35042 Rennes, France

[2] Univ Rennes 1, Inst Sci Chim Rennes, Team Ctr Diffractomtrie X, CNRS,UR1,UMR 6226, F-35042 Rennes, France

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2012年 / 354卷 / 10期

关键词：

alcohols; esters; hydrosilylation; iron catalysis; reduction; CARBOXYLIC-ACID DERIVATIVES; METAL HYDRIDE CATALYSTS; EFFICIENT HYDROSILYLATION; SELECTIVE REDUCTION; CARBONYL-COMPOUNDS; ASYMMETRIC HYDROSILYLATION; HYDROSILANE REDUCTION; PINCER LIGANDS; KETONES; ALCOHOLS;

D O I：

10.1002/adsc.201200087

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The first hydrosilylation of esters catalyzed by a well defined iron complex has been developed. Esters are converted to the corresponding alcohols at 100?degrees C, under solvent-free conditions and visible light activation.

引用

页码：1879 / 1884

页数：6

共 79 条

[1]

Addis, 2011, ANGEW CHEM, V123, P6128

[2] Selective Reduction of Carboxylic Acid Derivatives by Catalytic Hydrosilylation [J].