Practical and efficient 1 alpha-hydroxylation of 4,4-dimethyl-2-ene derivatives in terpenic series.

被引：13

作者：

Aranda, G

BertranneDelahaye, M

Azerad, R

Maurs, M

Cortes, M

Ramirez, H

Vernal, G

Prange, T

机构：

[1] UNIV PARIS 06,CHIM & BIOCHIM PHARMACOL & TOXICOL LAB,F-75006 PARIS,FRANCE

[2] PONTIFICIA UNIV CATOLICA CHILE,FAC QUIM,SANTIAGO,CHILE

[3] URA 1430,F-93017 BOBIGNY,FRANCE

来源：

SYNTHETIC COMMUNICATIONS | 1997年 / 27卷 / 01期

关键词：

D O I：

10.1080/00397919708004804

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The third part of a triptycal synthesis providing 1 alpha-hydroxy compounds, through microbial hydroxylation in position-3 of terpenoid substrates, followed by dehydration to 4,4-dimethyl-2-ene compounds and subsequent allylic hydroxylation by SeO2/pyridine N-oxide, is described.

引用

页码：45 / 60

页数：16

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