Porphine dimeric assemblies in organic-pillared coordination cages

被引：128

作者：

Ono, Kosuke

Yoshizawa, Michito

Kato, Tatsuhisa

Watanabe, Kentaro

Fujita, Makoto

机构：

[1] Univ Tokyo, Sch Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1138656, Japan

[2] Josai Univ, Fac Sci, Sakado, Saitama 3500295, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 11期

关键词：

cage compounds; EPR spectroscopy; host-guest systems; pi interactions; porphyrinoids;

D O I：

10.1002/anie.200604790

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) A box of porphine pi: Two types of porphine dimeric assemblies (A and B) are formed in the box-shaped cavity of organic-pillared Pd coordination cages. Depending on the cavity size (see picture, right), the two porphine molecules are π-stacked directly (A) or layered with an aromatic spacer (B). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：1803 / 1806

页数：4

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