Silver(I) scorpionate mediated insertion of carbenes into aliphatic C-H bonds

被引：98

作者：

Dias, HVR ^{[1
]}

Browning, RG ^{[1
]}

Richey, SA ^{[1
]}

Lovely, CJ ^{[1
]}

机构：

[1] Univ Texas, Dept Chem & Biochem, Arlington, TX 76019 USA

来源：

ORGANOMETALLICS | 2004年 / 23卷 / 06期

关键词：

D O I：

10.1021/om0499198

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Silver(I) adducts featuring highly fluorinated tris(pyrazolyl)borate, [HB(3,5-(CF3)(2)Pz)(3)](-), catalyze the carbene insertion into carbon-hydrogen bonds of cyclic and acyclic hydrocarbons at room temperature. These silver complexes are more effective than related copper catalysts such as [HB(3,5-(CF3)(2)Pz)(3)]Cu(THF) for hydrocarbon activation via this route.

引用

页码：1200 / 1202

页数：3

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