A simple and efficient method for epoxidation of terminal alkenes

被引：196

作者：

Coperet, C ^{[1
]}

Adolfsson, H ^{[1
]}

Sharpless, KB ^{[1
]}

机构：

[1] Scripps Res Inst, DEPT CHEM, LA JOLLA, CA 92037 USA

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 16期

关键词：

D O I：

10.1039/a703542j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The use of a catalytic amount of 3-cyanopyridine in the methyltrioxorhenium catalysed epoxidation of terminal alkenes with aqueous hydrogen peroxide speeds turnover, which results in the formation of many functionalized epoxides in high yields.

引用

页码：1565 / 1566

页数：2

共 30 条

[21] RUDOLPH J, 1997, J AM CHEM SOC, V119, P6185
[22] A halide-free method for olefin epoxidation with 30% hydrogen peroxide
Sato, K
Aoki, M
Ogawa, M
Hashimoto, T
Panyella, D
Noyori, R
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1997, 70 (04) : 905 - 915
[23] A practical method for epoxidation of terminal olefins with 30% hydrogen peroxide under halide-free conditions
Sato, K
Aoki, M
Ogawa, M
Hashimoto, T
Noyori, R
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1996, 61 (23) : 8310 - 8311
[24] Sharpless K.B., 1979, ALDRICHIM ACTA, V12, P63
[25] SHELDON RA, 1996, APPL HOMOGENEOUS CAT
[26] Strukul G., 1992, CATALYTIC OXIDATIONS
[27] A NEW, EFFECTIVE CATALYTIC-SYSTEM FOR EPOXIDATION OF OLEFINS BY HYDROGEN-PEROXIDE UNDER PHASE-TRANSFER CONDITIONS
VENTURELLO, C
ALNERI, E
RICCI, M
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1983, 48 (21) : 3831 - 3833
[28] QUATERNARY AMMONIUM TETRAKIS(DIPEROXOTUNGSTO)PHOSPHATES(3-) AS A NEW CLASS OF CATALYSTS FOR EFFICIENT ALKENE EPOXIDATION WITH HYDROGEN-PEROXIDE
VENTURELLO, C
DALOISIO, R
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (07) : 1553 - 1557
[29] Methyltrioxorhenium-catalyzed oxidation of secondary and primary amines with hydrogen peroxide
Yamazaki, S
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1997, 70 (04) : 877 - 883
[30] KINETICS AND MECHANISM OF OXIDATION OF ANILINES BY HYDROGEN-PEROXIDE AS CATALYZED BY METHYLRHENIUM TRIOXIDE
ZHU, ZL
ESPENSON, JH
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (05) : 1326 - 1332

← 1 2 3 →