Stabilisation of a paramagnetic BH4--bridged dinickel(II) complex by a macrodinucleating hexaaza-dithiophenolate ligand

被引：42

作者：

Journaux, Y

Lozan, V

Klingele, J

Kersting, B

机构：

[1] Univ Paris 06, CNRS, UMR 7071, Lab Chim Inorgan & Mat, F-75252 Paris 05, France

[2] Univ Leipzig, Inst Anorgan Chem, D-04013 Leipzig, Germany

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 01期

关键词：

D O I：

10.1039/b512744k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first paramagnetic borohydrido-bridged dinuclear nickel(II) complex, [(L)Ni-2(II)(mu(1,3)-BH4)](+), stabilised by a sterically demanding hexaaza-dithiophenolate macrocycle, has been obtained by the reaction of [(L)Ni-2(II)(m-ClO4)](+) with (NBu4BH4)-Bu-n.

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页码：83 / 84

页数：2

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