Can plasma spectrochemistry assist in improving the accuracy of chemical analysis?

被引:8
作者
Adams, F [1 ]
Adriaens, A [1 ]
Bogaerts, A [1 ]
机构
[1] Univ Instelling Antwerp, Micro & Trace Anal Ctr, B-2610 Wilrijk, Belgium
关键词
chemical analysis; plasma spectrochemistry; reliability; metrology;
D O I
10.1016/S0003-2670(02)00010-7
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The validity of data produced in chemical analysis must be properly guaranteed for their quality as analytical results are far from being accurate. There is a growing pressure to improve the overall quality of analytical information and to make it consistent with general metrological principles. Plasma spectrochemical methods are evaluated in their ability to increase the accuracy of analysis, to serve eventually as definite methods of analysis and to assist in the elaboration of certified reference materials. Possibilities reside in the application of isotope dilution mass spectrometry and in increasing the knowledge of the fundamental processes governing ion and photon formation so that they become able to describe fully the processes which link analytical signals with concentration. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:63 / 75
页数:13
相关论文
共 48 条
[1]   INORGANIC MASS-SPECTROMETRY OF SOLID SAMPLES [J].
ADAMS, F ;
VERTES, A .
FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY, 1990, 337 (06) :638-647
[2]   Improving the reliability of speciation analysis of organometallic compounds [J].
Adams, F ;
Slaets, S .
TRAC-TRENDS IN ANALYTICAL CHEMISTRY, 2000, 19 (2-3) :80-85
[3]  
ADAMS F, 2000, ENCY ANAL CHEM, V15, P13636
[4]  
[Anonymous], [No title captured]
[5]   Precise and accurate isotope ratio measurements by ICP-MS [J].
Becker, JS ;
Dietze, HJ .
FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY, 2000, 368 (01) :23-30
[6]   Methyl mercury revisited [J].
Bloom, NS ;
Evans, D ;
Hintelmann, H ;
Wilken, RD .
ANALYTICAL CHEMISTRY, 1999, 71 (17) :575A-575A
[7]   Artifact formation of methyl mercury during aqueous distillation and alternative techniques for the extraction of methyl mercury from environmental samples [J].
Bloom, NS ;
Colman, JA ;
Barber, L .
FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY, 1997, 358 (03) :371-377
[8]  
BLOOM NS, 1997, FRESEN J ANAL CHEM, P358
[9]   Relative sensitivity factors in glow discharge mass spectrometry: The role of charge transfer ionization [J].
Bogaerts, A ;
Gijbels, R .
JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 1996, 11 (09) :841-847
[10]   Comparison of calculated and measured optical emission intensities in a direct current argon-copper glow discharge [J].
Bogaerts, A ;
Donko, Z ;
Kutasi, K ;
Bano, G ;
Pinhao, N ;
Pinheiro, M .
SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 2000, 55 (09) :1465-1479