Characterisation and application of the electrochemical plate microreactor in analytical chemistry

被引：7

作者：

Ernst, H ^{[1
]}

Ross, B ^{[1
]}

Knoll, M ^{[1
]}

机构：

[1] Univ Munster, Inst Chemo & Biosensorik EV, D-48149 Munster, Germany

来源：

ELECTROCHIMICA ACTA | 2002年 / 47卷 / 11期

关键词：

amperometric biosensor; mathematical modelling; mass transport; potential drop; plate cell;

D O I：

10.1016/S0013-4686(02)00010-5

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Different volumetric flow rates and various reactor configurations were studied in order to characterise the flow-through plate microreactor. The reactor is fabricated in silicon microsystem technology. The investigations focus on the determination and modelling of the fractional conversion and the potential drop over the reactor surface. Both parameters are necessary to size electrochemical reactors. The performance of the electrochemical reactor correlates strongly to mathematical equations derided from the fluid hydrodynamic theory. The standard deviation (S.D.) of the measured and calculated performance is 2.8%. These results suggest that equations derived in conventional reactor technology are applicable in microsystems. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：1795 / 1800

页数：6

共 19 条

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