Synthesis of organometallic solids by protonation of Cp*M(CN)3n- (M = Rh, Ir, Ru)

被引：5

作者：

Contakes, SM

Schmidt, M

Rauchfuss, TB ^{[1
]}

机构：

[1] Univ Illinois, Sch Chem Sci, Urbana, IL 61801 USA

[2] Univ Illinois, Frederick Seitz Mat Res Lab, Urbana, IL 61801 USA

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 13期

关键词：

D O I：

10.1039/a902115i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Protonation of aqueous acetone solutions of [Cp*Ir(CN)(3)](-) produces the two-dimensional organometallic solid (H3O)-[Cp*Ir(CN)(3)]. Me2CO wherein 14 Angstrom diameter channels (Ir4C8N8O4) contain exchangeable solvent molecules; the analogous Ru and Rh tricyanide complexes are also susceptible to proton-induced polymerization.

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页码：1183 / 1184

页数：2

相关论文

共 19 条

[1] Hydrogen bonding in organometallic crystals - a survey [J].

Braga, D ;

Grepioni, F ;

Desiraju, GR .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1997, 548 (01) :33-43

[2] Synthesis of novel liquid crystalline organometallic polymers [J].

Bunz, UHF .

PURE AND APPLIED CHEMISTRY, 1996, 68 (02) :309-312

[3] The seven-component assembly of the bowl-shaped cages CP*7Rh7(CN)122+ and Cp*7Rh3Ir4(CN)122+ [J].

Contakes, SM ;

Klausmeyer, KK ;

Milberg, RM ;

Wilson, SR ;

Rauchfuss, TB .

ORGANOMETALLICS, 1998, 17 (17) :3633-3635

[4] MOLECULAR CONTAINER COMPOUNDS [J].

CRAM, DJ .

NATURE, 1992, 356 (6364) :29-36

[5]

CRAM DJ, 1987, CHEMTECH, V17, P120

[6] Transition-metal-directed assembly of well-defined organic architectures possessing large voids: From macrocycles to [2]catenanes [J].

Fujita, M ;

Ogura, K .

COORDINATION CHEMISTRY REVIEWS, 1996, 148 :249-264

[7]

Gorman C, 1998, ADV MATER, V10, P295, DOI 10.1002/(SICI)1521-4095(199803)10:4<295::AID-ADMA295>3.0.CO

[8]

2-N

[9] Molecular Prussian Blue analogues:: synthesis and structure of cubic Cr4Co4(CN)12 and Co8(CN)12 clusters [J].

Heinrich, JL ;

Berseth, PA ;

Long, JR .

CHEMICAL COMMUNICATIONS, 1998, (11) :1231-1232

[10] Alkali metal-templated assembly of cyanometalate "boxes" (NEt4)3{M[Cp*Rh(CN)3]4[Mo(CO)3]4} (M = K, Cs).: Selective binding of Cs+ [J].

Klausmeyer, KK ;

Wilson, SR ;

Rauchfuss, TB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (12) :2705-2711