Corrosion inhibition of a carbon steel in 2M H3PO4 medium by "triazine" compounds

被引:39
作者
Bekkouch, K [1 ]
Aouniti, A
Hammouti, B
Kertit, S
机构
[1] Fac Sci Oujda, Lab Chim Eaux & Corros, Oujda, Morocco
[2] Fac Sci Oujda, Lab Chim Solide Mineral, Oujda, Morocco
[3] Ecole Normale Super Takaddoum, UREF, Lab Physicochim Mat, AUPELF,LAF 502, Rabat, Morocco
关键词
corrosion; inhibition; steel; H3PO4; triazine;
D O I
10.1051/jcp:1999174
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
The effect of addition of some triazine compounds on the corrosion behaviour of steel in 2M H3PO4 has been studied by weight loss and electrochemical polarisation methods, Both methods showed that the dissolution rate was dependent on the chemical properties and concentration of the product. From comparison of results, it was found that 6-azathymine (T6) is the best inhibitor and its inhibition efficiency reaches a maximum value of 86% at 10(-3)M. Polarisation measurements indicated that T6 acts as cathodic inhibitor by merely blocking the reaction sites without changing the mechanism of the hydrogen evolution reaction, It was found that T6 was adsorbed on steel surface according to a Langmuir isotherm model. The effect of temperature indicated that inhibition efficiency of T6 is dependent on the temperature in the range 25 - 50 degrees C.
引用
收藏
页码:838 / 850
页数:13
相关论文
共 10 条
[1]   Inhibition of the acid corrosion of iron with new pyrazole derivatives [J].
Aouniti, A ;
Hammouti, B ;
Brighli, M ;
Kertit, S ;
Berhili, F ;
ElKadiri, S ;
Ramdani, A .
JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE, 1996, 93 (7-8) :1262-1280
[2]  
AOUNITI A, 1995, THESIS U MOHAMED 1 M
[3]  
BADAWY WA, 1989, CORROSION, V46, P978
[4]  
GHOMAS JGN, 1981, 5 EUR S CORR INH ANN, P453
[5]   Corrosion inhibition of iron in 1M HCl by 1-phenyl-5-mercapto-1,2,3,4-tetrazole [J].
Kertit, S ;
Hammouti, B .
APPLIED SURFACE SCIENCE, 1996, 93 (01) :59-66
[6]  
KERTIT S, 1993, THESIS U IBN TOFAIL
[7]   CORROSION INHIBITION OF A 70/30 CUPRONICKEL IN A 3-PERCENT NACL MEDIUM BY VARIOUS AZOLES [J].
LAACHACH, A ;
AOUIAL, M ;
SRHIRI, A ;
BENBACHIR, A .
JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE, 1992, 89 (10) :2011-2027
[8]   INHIBITION OF THE ACID CORROSION OF STEEL BY 4-AMINO-3-HYDRAZINO-5-THIO-1,2,4-TRIAZOLES [J].
TADROS, AB ;
ABDELNABEY, BA .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1988, 246 (02) :433-439
[9]   N-HETEROCYCLIC COMPOUNDS AS CORROSION-INHIBITORS FOR ALUMINUM COPPER ALLOY IN HYDROCHLORIC-ACID [J].
TALATI, JD ;
GANDHI, DK .
CORROSION SCIENCE, 1983, 23 (12) :1315-1332
[10]   CHEMISORPTION OF A COMPACT POLYMERIC COATING ON COPPER SURFACES FROM A BENZOTRIAZOLE SOLUTION [J].
XUE, G ;
DING, JF .
APPLIED SURFACE SCIENCE, 1990, 40 (04) :327-332