Convergent synthesis of a polyfunctionalized fullerene by regioselective five-fold addition of a functionalized organocopper reagent to C60

被引：43

作者：

Zhong, YW ^{[1
]}

Matsuo, Y ^{[1
]}

Nakamura, E ^{[1
]}

机构：

[1] Univ Tokyo, Nakamura Funct Carbon Cluster Project, ERATO, Japan Sci & Technol Agcy JST,Bunkyo Ku, Tokyo 1130033, Japan

来源：

ORGANIC LETTERS | 2006年 / 8卷 / 07期

关键词：

D O I：

10.1021/ol060282t

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A method for one-step preparation of polyfunctionalized fullerene derivatives by regioselective penta-addition of an organocopper reagent is described. A functionalized aryl iodide is first converted to the corresponding Grignard reagent and then to a copper reagent and finally is allowed to react with C-60. The method allows introduction of five functional groups to the C-60 skeleton in a convergent manner. The shuttlecock-like molecules crystallize into a columnar packing structure.

引用

页码：1463 / 1466

页数：4

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