Nanostructured carbon-metal oxide composite electrodes for supercapacitors: a review

被引:1860
作者
Zhi, Mingjia [1 ]
Xiang, Chengcheng [1 ]
Li, Jiangtian [1 ]
Li, Ming [1 ]
Wu, Nianqiang [1 ]
机构
[1] W Virginia Univ, Dept Mech & Aerosp Engn, Morgantown, WV 26505 USA
关键词
ATOMIC LAYER DEPOSITION; CORE-SHELL NANOWIRES; MANGANESE-DIOXIDE; ACTIVATED CARBONS; HIGH-ENERGY; HIGH-POWER; HYDROTHERMAL SYNTHESIS; NANOFIBER ELECTRODES; HIGH-MASS; GRAPHENE;
D O I
10.1039/c2nr32040a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This paper presents a review of the research progress in the carbon-metal oxide composites for supercapacitor electrodes. In the past decade, various carbon-metal oxide composite electrodes have been developed by integrating metal oxides into different carbon nanostructures including zero-dimensional carbon nanoparticles, one-dimensional nanostructures (carbon nanotubes and carbon nanofibers), two-dimensional nanosheets (graphene and reduced graphene oxides) as well as three-dimensional porous carbon nano-architectures. This paper has described the constituent, the structure and the properties of the carbon-metal oxide composites. An emphasis is placed on the synergistic effects of the composite on the performance of supercapacitors in terms of specific capacitance, energy density, power density, rate capability and cyclic stability. This paper has also discussed the physicochemical processes such as charge transport, ion diffusion and redox reactions involved in supercapacitors.
引用
收藏
页码:72 / 88
页数:17
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共 143 条
[51]  
Koch V. R., 2005, RECENT ADV ELECTROLY
[52]   Electrochemical fabrication of a porous nanostructured nickel hydroxide film electrode with superior pseudocapacitive performance [J].
Kong, De-Shuai ;
Wang, Jian-Ming ;
Shao, Hai-Bo ;
Zhang, Jian-Qing ;
Cao, Chu-nan .
JOURNAL OF ALLOYS AND COMPOUNDS, 2011, 509 (18) :5611-5616
[53]   Chemical synthesis of Fe2O3 thin films for supercapacitor application [J].
Kulal, P. M. ;
Dubal, D. P. ;
Lokhande, C. D. ;
Fulari, V. J. .
JOURNAL OF ALLOYS AND COMPOUNDS, 2011, 509 (05) :2567-2571
[54]   Battery-ultracapacitor hybrids for pulsed current loads: A review [J].
Kuperman, Alon ;
Aharon, Ilan .
RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2011, 15 (02) :981-992
[55]   Nanoporous metal/oxide hybrid electrodes for electrochemical supercapacitors [J].
Lang, Xingyou ;
Hirata, Akihiko ;
Fujita, Takeshi ;
Chen, Mingwei .
NATURE NANOTECHNOLOGY, 2011, 6 (04) :232-236
[56]   Nickel oxide/carbon nanotubes nanocomposite for electrochemical capacitance [J].
Lee, JY ;
Liang, K ;
An, KH ;
Lee, YH .
SYNTHETIC METALS, 2005, 150 (02) :153-157
[57]   Carbon Nanotube/Manganese Oxide Ultrathin Film Electrodes for Electrochemical Capacitors [J].
Lee, Seung Woo ;
Kim, Junhyung ;
Chen, Shuo ;
Hammond, Paula T. ;
Shao-Horn, Yang .
ACS NANO, 2010, 4 (07) :3889-3896
[58]   Ultrathin MnO2 nanofibers grown on graphitic carbon spheres as high-performance asymmetric supercapacitor electrodes [J].
Lei, Zhibin ;
Zhang, Jintao ;
Zhao, X. S. .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (01) :153-160
[59]   Single-crystalline Ni(OH)2 and NiO nanoplatelet arrays as supercapacitor electrodes [J].
Li, Jiangtian ;
Zhao, Wei ;
Huang, Fuqiang ;
Manivannan, Ayyakkannu ;
Wu, Nianqiang .
NANOSCALE, 2011, 3 (12) :5103-5109
[60]   Flexible graphene/MnO2 composite papers for supercapacitor electrodes [J].
Li, Zhangpeng ;
Mi, Yongjuan ;
Liu, Xiaohong ;
Liu, Sheng ;
Yang, Shengrong ;
Wang, Jinqing .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (38) :14706-14711