Synthesis of mesoporous tungsten carbide by an impregnation-compaction route, and its NH3 decomposition catalytic activity

被引：35

作者：

Cui, Xiangzhi ^{[1
]}

Li, Hua ^{[2
]}

Guo, Limin ^{[1
]}

He, Dannong ^{[3
]}

Chen, Hangrong ^{[1
]}

Shi, Jianlin ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China

[2] Suzhou Univ, Suzhou 215021, Peoples R China

[3] Natl Engn Res Ctr Nanotechnol, Shanghai, Peoples R China

来源：

DALTON TRANSACTIONS | 2008年 / 45期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1039/b809923e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A mesoporous tungsten carbide (WC) with high surface area (138 m(2) g(-1)) has been synthesized at 700 degrees C using a modified template replicating route in which the pore entrances were sealed under external pressure after the W source impregnation. X-Ray diffraction (XRD), transmission electron microscopy (TEM),field emission scanning electron microscopy (FE-SEM), energy-dispersive X-ray (EDX) spectroscopy and nitrogen sorption techniques were employed to characterize the replicated material. The prepared tungsten carbide with high surface area is well crystallized and has a partially ordered mesoporous structure. Temperature programmed reaction (TPR) and time-on-stream (TOS) results show that the prepared mesoporous tungsten carbide has high and stable catalytic activity for the decomposition reaction of NH3, and the complete NH3 decomposition temperature was obtained at 500 degrees C. This mesoporous WC appears to be a good catalyst for use for NH3 decomposition.

引用

页码：6435 / 6440

页数：6

共 29 条

[1] Diatom-templated synthesis of ordered meso/macroporous hierarchical materials [J].

Cai, Xiaohui ;

Zhu, Guangshan ;

Zhang, Weiwei ;

Zhao, Huanyu ;

Wang, Ce ;

Qiu, Shilun ;

Wei, Yen .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2006, (18) :3641-3645

[2] Templated synthesis of hierarchically porous manganese oxide with a crystalline nanorod framework and its high electrochemical performance [J].

Chen, Hangrong ;

Dong, Xiaoping ;

Shi, Jianlin ;

Zhao, Jinjin ;

Hua, Zile ;

Gao, Jianhua ;

Ruan, Meiling ;

Yan, Dongsheng .

JOURNAL OF MATERIALS CHEMISTRY, 2007, 17 (09) :855-860

[3] A composite surfactant route for the synthesis of thermally stable and hierarchically porous zirconia with a nanocrystallized framework [J].

Chen, HR ;

Gu, JL ;

Shi, JL ;

Liu, ZC ;

Gao, JH ;

Ruan, ML ;

Yan, DS .

ADVANCED MATERIALS, 2005, 17 (16) :2010-+

[4] Catalytic ammonia decomposition:: COx-free hydrogen production for fuel cell applications [J].

Choudhary, TV ;

Sivadinarayana, C ;

Goodman, DW .

CATALYSIS LETTERS, 2001, 72 (3-4) :197-201

[5] New catalysts for the conversion of methane to synthesis gas: Molybdenum and tungsten carbide [J].

Claridge, JB ;

York, APE ;

Brungs, AJ ;

Marquez-Alvarez, C ;

Sloan, J ;

Tsang, SC ;

Green, MLH .

JOURNAL OF CATALYSIS, 1998, 180 (01) :85-100

[6]

Dong AG, 2002, ADV MATER, V14, P926, DOI 10.1002/1521-4095(20020618)14:12<926::AID-ADMA926>3.0.CO

[7]

2-1

[8] High-temperature removal of NH3, organic sulfur, HCl, and tar component from coal-derived gas [J].

Dou, BL ;

Zhang, MC ;

Gao, JS ;

Shen, WQ ;

Sha, XZ .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2002, 41 (17) :4195-4200

[9] Platinized mesoporous tungsten carbide for electrochemical methanol oxidation [J].

Ganesan, Raman ;

Ham, Dong Jin ;

Lee, Jae Sung .

ELECTROCHEMISTRY COMMUNICATIONS, 2007, 9 (10) :2576-2579

[10] Synthesis of crystalline mesoporous CdS semiconductor nanoarrays through a mesoporous SBA-15 silica template technique [J].

Gao, F ;

Lu, QY ;

Zhao, DY .

ADVANCED MATERIALS, 2003, 15 (09) :739-742

← 1 2 3 →