Reversible formal insertion of CO2 into a remote C-H bond of a ligand in a Ru(II) complex at room temperature

被引：25

作者：

Annibale, Vincent T. ^{[1
]}

Song, Datong ^{[1
]}

机构：

[1] Univ Toronto, Dept Chem, Davenport Chem Res Labs, Toronto, ON M5S 3H6, Canada

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 44期

基金：

加拿大自然科学与工程研究理事会;

关键词：

CARBON-DIOXIDE; CONVERSION; CAPTURE; BINDING;

D O I：

10.1039/c2cc17933d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Here we report a reversible formal insertion of CO2 into a remote C-H bond of the diazafluorenide ligand (L-) in a Ru(II) complex which occurs at ambient temperature.

引用

页码：5416 / 5418

页数：3

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