Highly Selective CO2 Capture in Flexible 3D Coordination Polymer Networks

被引：357

作者：

Choi, Hye-Sun ^{[1
]}

Suh, Myunghyun Paik ^{[1
]}

机构：

[1] Seoul Natl Univ, Dept Chem, Seoul 151747, South Korea

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 37期

关键词：

adsorption; carbon dioxide capture; macrocyclic complexes; nickel; organic-inorganic hybrid composites; METAL-ORGANIC FRAMEWORK; ZEOLITIC IMIDAZOLATE FRAMEWORKS; SINGLE-CRYSTAL TRANSFORMATIONS; ION-EXCHANGE PROPERTIES; BILAYER OPEN FRAMEWORK; CARBON-DIOXIDE; PALLADIUM NANOPARTICLES; ADSORPTION SELECTIVITY; MACROCYCLIC COMPLEXES; SORPTION PROPERTIES;

D O I：

10.1002/anie.200902836

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Keeping limber: Three-dimensional coordination polymers incorporating flexible pillars (see picture, left) exhibit highly selective adsorption of CO2 over N2, H2, and CH4 (see picture, right), thermal stability up to 300 °C, as well as air and water stability, and allow efficient CO2 capture, storage, and sensing. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：6865 / 6869

页数：5

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