On-surface covalent coupling in ultrahigh vacuum

被引：194

作者：

Gourdon, Andre ^{[1
]}

机构：

[1] CEMES, CNRS, Nanosci Grp, F-31005 Toulouse 04, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 37期

关键词：

C-C coupling; carbenes; radical reactions; scanning probe microscopy; surface chemistry;

D O I：

10.1002/anie.200802229

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Beyond supramolecular self-assembly: On-surface covalent coupling of organic precursors is a powerful method to obtain 1D or 2D robust molecular arrays on a substrate (see picture) that have numerous potential applications in nanotechnology. Significant advances have recently been made in this field including imine formation, dehydration of boronic acids, esterification, as well as radical and carbene coupling reactions. (Figure Presented) © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：6950 / 6953

页数：4

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