Tin(II) chloride mediated allylation of aldimines generated in situ with allylstannane in water

被引:42
作者
Akiyama, T
Onuma, Y
机构
[1] Toshima-ku, Tokyo 171-8588, 1-5-1, Mejir
来源
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 2002年 / 09期
关键词
D O I
10.1039/b202486a
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Three-component synthesis of homoallylic amines starting from aldehyde, amine, and allyltributylstannane were realized by means of tin(II) chloride dihydrate in water in the presence of SDS.
引用
收藏
页码:1157 / 1158
页数:2
相关论文
共 35 条
  • [1] Chemoselective allylation of aldimine with allyltriethylgermane by the combined use of BF3•OEt2 and AcOH
    Akiyama, T
    Iwai, J
    Onuma, Y
    Kagoshima, H
    [J]. CHEMICAL COMMUNICATIONS, 1999, (21) : 2191 - 2192
  • [2] Akiyama T, 1998, SYNLETT, P273
  • [3] A highly stereo-divergent Mannich-type reaction catalyzed by Bronsted acid in aqueous media
    Akiyama, T
    Takaya, J
    Kagoshima, H
    [J]. TETRAHEDRON LETTERS, 2001, 42 (24) : 4025 - 4028
  • [4] Bronsted acid-catalyzed aza Diels-Alder reaction of Danishefsky's diene with aldimine generated in situ from aldehyde and amine in aqueous media
    Akiyama, T
    Takaya, J
    Kagoshima, H
    [J]. TETRAHEDRON LETTERS, 1999, 40 (44) : 7831 - 7834
  • [5] Chemoselective activation of aldimine in preference to aldehyde by the combination of BF3•OEt2 and water:: Novel catalyst for the Mannich-type reaction
    Akiyama, T
    Takaya, J
    Kagoshima, H
    [J]. CHEMISTRY LETTERS, 1999, (09) : 947 - 948
  • [6] Akiyama T, 1999, SYNLETT, P1426
  • [7] HBF4 catalyzed Mannich-type reaction in aqueous media
    Akiyama, T
    Takaya, J
    Kagoshima, H
    [J]. SYNLETT, 1999, (07) : 1045 - 1048
  • [8] Syn diastereoselectivity in the synthesis of homoallylamine using crotylsilane in the three-component reaction
    Billet, M
    Klotz, P
    Mann, A
    [J]. TETRAHEDRON LETTERS, 2001, 42 (04) : 631 - 634
  • [9] Gastner T, 2001, ANGEW CHEM INT EDIT, V40, P1896, DOI 10.1002/1521-3773(20010518)40:10<1896::AID-ANIE1896>3.3.CO
  • [10] 2-N