Chelation-assisted rhodium hydride-catalyzed regioselective H/D exchange in arenes

被引：33

作者：

Chen, Shanshan ^{[1
]}

Song, Guoyong ^{[1
]}

Li, Xingwei ^{[1
]}

机构：

[1] Nanyang Technol Univ, Sch Phys & Math Sci, Div Chem & Biol Chem, Singapore 637371, Singapore

来源：

TETRAHEDRON LETTERS | 2008年 / 49卷 / 48期

关键词：

D O I：

10.1016/j.tetlet.2008.09.122

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of air stable rhodium(III) hydride complexes are synthesized Via cyclometalation of functionalized arenes, and are active catalysts for regioselective H/D exchange in various arenes via chelation-assisted C-H activation in acetone-d(6). (C) 2008 Elsevier Ltd. All rights reserved.

引用

页码：6929 / 6932

页数：4

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