A General Palladium-Catalyzed Suzuki-Miyaura Coupling of Aryl Mesylates

被引：174

作者：

So, Chau Ming ^{[1
]}

Lau, Chak Po ^{[1
]}

Kwong, Fuk Yee ^{[1
]}

机构：

[1] Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Inst Mol Technol Drug Discovery & Synth, Open Lab Chirotechnol, Kowloon, Hong Kong, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 42期

关键词：

cross-coupling; homogeneous catalysis; mesylates; palladium; phosphanes;

D O I：

10.1002/anie.200803193

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Catalyze this! The first palladium-catalyzed Suzuki-Miyaura coupling of unactivated aryl mesylates is reported, with not only arylboronic acids, but also other organoboron nucleophiles (see picture; Z=B(OH)2, BF3K, BPin). The reaction conditions are compatible with various common functional groups (R1=alkyl, OMe, CHO, CO, CN, CO2R′, heteroaryl). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：8059 / 8063

页数：5

共 52 条

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