Polyamino acids as catalysts in asymmetric synthesis

被引:83
作者
Porter, MJ [1 ]
Roberts, SM [1 ]
Skidmore, J [1 ]
机构
[1] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England
关键词
amino acids and derivatives; peptides and polypeptides; polymers; reviews;
D O I
10.1016/S0968-0896(99)00144-3
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
The use of polyamino acids in asymmetric organic synthesis is reviewed. Particular emphasis is placed on the asymmetric epoxidation of alpha,beta-unsaturated ketones with hydrogen peroxide in the presence of polyalanine or polyleucine, and further transformations of the epoxide products. (C) 1999 Elsevier Science Ltd. All rights reserved.
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页码:2145 / 2156
页数:12
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