High-pressure vapor-liquid equilibrium for the binary systems carbon dioxide plus dimethyl sulfoxide and carbon dioxide plus dichloromethane

被引:29
作者
Vega-Gonzalez, A [1 ]
Tufeu, R [1 ]
Subra, P [1 ]
机构
[1] Univ Paris 13, Lab Ingn Mat & Hautes Pressions, CNRS, Inst Galilee, F-93430 Villetaneuse, France
关键词
D O I
10.1021/je010202q
中图分类号
O414.1 [热力学];
学科分类号
摘要
High-pressure vapor-liquid equilibrium data were measured for two binary systems: carbon dioxide + dimethyl sulfoxide at four temperatures from 309 to 329 K and pressures up to 13 MPa, and carbon dioxide + dichloromethane at 311.41 K and 326.95 K and pressures up to 9.5 MPa, Bubble points were determined by a synthetic method where a mixture of known composition is prepared in a sapphire cell of variable volume, The reliability of the equipment and method was established through comparison with literature on the carbon dioxide + ethanol system. These measurements were made at 314.45 and 324.17 K.
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页码:492 / 495
页数:4
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