Magnetism origin of Mn-doped ZnO nanoclusters

被引:94
作者
Li, JH
Shen, DZ
Zhang, JY
Zhao, DX
Li, BS
Lu, YM
Liu, YC
Fan, XW
机构
[1] Chinese Acad Sci, Changchun Inst Opt Fine Mech & Phys, Key Lab Excited State Proc, Changchun 130033, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100864, Peoples R China
[3] NE Normal Univ, Ctr Adv Optoelect Funct Mat Res, Changchun 130024, Peoples R China
基金
中国国家自然科学基金;
关键词
ZnMnO nanoclusters; room temperature ferromagnetism; magnetism origin; ZnMn2O4; ROOM-TEMPERATURE; FERROMAGNETISM; FILMS;
D O I
10.1016/j.jmmm.2005.08.025
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
ZnMnO nanoclusters were synthesized by the sot-gel method. The structural and magnetic characters were investigated. The XRD spectrum shows ZnMnO nanoclusters are hexagonal wurtzite structures and a small quantity of ZnMn2O4 phase is also present in the spectrum. The percentages of Zn and Mn elements in the ZnMnO nanostructure are 97% and 3%, respectively, which are induced from XPS data. EPR spectrum with g = 1.9961 shows the signal of Mn2+. The magnetization curve measured at room temperature shows a hysteresis loop. XRD and XPS analyses prove that ferromagnetic ordering arises from ZnMn2O4 in all probability. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:118 / 121
页数:4
相关论文
共 15 条
[1]   High-pressure phase transition and properties of spinel ZnMn2O4 [J].
Åsbrink, S ;
Waskowska, A ;
Gerward, L ;
Olsen, JS ;
Talik, E .
PHYSICAL REVIEW B, 1999, 60 (18) :12651-12656
[2]   Synthesis, optical, and magnetic properties of diluted magnetic semiconductor Zn1-xMnxO nanowires via vapor phase growth [J].
Chang, YQ ;
Wang, DB ;
Luo, XH ;
Xu, XY ;
Chen, XH ;
Li, L ;
Chen, CP ;
Wang, RM ;
Xu, J ;
Yu, DP .
APPLIED PHYSICS LETTERS, 2003, 83 (19) :4020-4022
[3]   X-ray photoelectron spectroscopy and auger electron spectroscopy studies of Al-doped ZnO films [J].
Chen, M ;
Wang, X ;
Yu, YH ;
Pei, ZL ;
Bai, XD ;
Sun, C ;
Huang, RF ;
Wen, LS .
APPLIED SURFACE SCIENCE, 2000, 158 (1-2) :134-140
[4]   Zener model description of ferromagnetism in zinc-blende magnetic semiconductors [J].
Dietl, T ;
Ohno, H ;
Matsukura, F ;
Cibert, J ;
Ferrand, D .
SCIENCE, 2000, 287 (5455) :1019-1022
[5]   Ferromagnetic properties of Zn1-xMnxO epitaxial thin films [J].
Jung, SW ;
An, SJ ;
Yi, GC ;
Jung, CU ;
Lee, SI ;
Cho, S .
APPLIED PHYSICS LETTERS, 2002, 80 (24) :4561-4563
[6]   Formation and characterization of (Zn1-xMnx)O diluted magnetic semiconductors grown on (0001) Al2O3 substrates [J].
Kim, DS ;
Lee, S ;
Min, C ;
Kim, HM ;
Yuldashev, SU ;
Kang, TW ;
Kim, DY ;
Kim, TW .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 2003, 42 (12) :7217-7220
[7]   Synthesis and magnetic properties of Zn1-xMnxO films prepared by the sol-gel method [J].
Kim, YM ;
Yoon, M ;
Park, IW ;
Park, YJ ;
Lyou, JH .
SOLID STATE COMMUNICATIONS, 2004, 129 (03) :175-178
[8]   Ferromagnetism in Mn-implanted ZnO:Sn single crystals [J].
Norton, DP ;
Pearton, SJ ;
Hebard, AF ;
Theodoropoulou, N ;
Boatner, LA ;
Wilson, RG .
APPLIED PHYSICS LETTERS, 2003, 82 (02) :239-241
[9]   Dilute magnetic semiconducting oxides [J].
Pearton, SJ ;
Heo, WH ;
Ivill, M ;
Norton, DP ;
Steiner, T .
SEMICONDUCTOR SCIENCE AND TECHNOLOGY, 2004, 19 (10) :R59-R74
[10]   Stabilization of ferromagnetic states by electron doping in Fe-, Co- or Ni-doped ZnO [J].
Sato, K ;
Katayama-Yoshida, H .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS, 2001, 40 (4A) :L334-L336