Toward constructing nanoscale hydroxo-lanthanide clusters: syntheses and characterizations of novel tetradecanuclear hydroxo-lanthanide clusters

被引：92

作者：

Wang, RY ^{[1
]}

Song, DT ^{[1
]}

Wang, SM ^{[1
]}

机构：

[1] Queens Univ, Dept Chem, Kingston, ON K7L 3N6, Canada

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 04期

关键词：

D O I：

10.1039/b105969f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two novel tetradecanuclear hydroxo-lanthanide complexes, formulated as Ln(14)(mu(4)-OH)(2)(mu(3)-OH)(16)(mu-eta(2)-acac)(8)(eta(2)-acac)(16), Ln = Tb, 1; Eu, 2; acac = acetylacetonato, were synthesized and characterized by single-crystal X-ray diffraction, elemental analysis and phosphorescence spectroscopy.

引用

页码：368 / 369

页数：2

共 23 条

[21] Syntheses, structures, and luminescence of novel lanthanide complexes of tripyridylamine, N,N,N′,N′-tetra(2-pyridyl)-1,4-phenylenediamine and N,N,N′,N′-tetra(2-pyridyl)biphenyl-4,4′-diamine
Yang, WY
Chen, L
Wang, SN
[J]. INORGANIC CHEMISTRY, 2001, 40 (03) : 507 - 515
[22] Oxo-centered regular octahedral lanthanide clusters
Zhang, DS
Ma, BQ
Jin, TZ
Gao, S
Yan, CH
Mak, TCW
[J]. NEW JOURNAL OF CHEMISTRY, 2000, 24 (02) : 61 - 62
[23] Assembling lanthanide clusters under physiological or higher pH-conditions
Zheng, ZP
Wang, RY
[J]. COMMENTS ON INORGANIC CHEMISTRY, 2000, 22 (1-2) : 1 - +

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